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Q. A $1\,L$ glass flask contains some mercury. It is found that at different temperatures the volume of air inside the flask remains the same. What is the volume (in cc) of mercury in this flask if coefficient of linear expansion of glass is $9 \times 10^{-6}/^{\circ}C$ while of volume expansion of mercury is $1.8 \times 10^{-4}/^{\circ}C$?

Thermal Properties of Matter

Solution:

It is given that the volume of air in the flask remains the same. This means that the expansion in volume of the vessel is exactly equal to the volume expansion of mercury,
i.e., $\Delta V_G = \Delta V_L$
or $V_G \gamma _G \Delta \theta = V_L \gamma_L \Delta \theta$
$\therefore V_L = \frac{V_G \gamma_G}{\gamma_L}$
$ = \frac{1000 \times ( 3\times 9 \times 10^{-6})}{1. 8 \times 10^{-4}} $
$ = 150 \,cc$