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Chemistry
For certain first order reaction m, 75% of the reaction complete in 30 min. How much time it require to complete 99.9% of the reaction?
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Q. For certain first order reaction m, 75% of the reaction complete in 30 min. How much time it require to complete 99.9% of the reaction?
KCET
KCET 2001
Chemical Kinetics
A
$150\, min$
51%
B
$100\, min$
12%
C
$90\, min$
23%
D
$300\, min$
14%
Solution:
Its a 1st order reaction, So
$\frac{t_{x \%}}{t_{y \%}}=\frac{\log \frac{100}{100-x}}{\log \frac{100}{100-y}}$
Here $x \%=75 \%$ and $y \%=99.9 \%$
Substituting the values, We get
$\frac{30}{t_{y} \%}=\frac{\log \frac{100}{100-75}}{\log \frac{100}{100-99.9}}$
$t _{ y \%}=\frac{30}{0.2}=150 min$