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Q. $50\, mL$ of $0.5\, M$ oxalic acid is needed to neutralize $25\, mL$ of sodium hydroxide solution. The amount of $NaOH$ in $50\, mL$ of the given sodium hydroxide solution is :

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Solution:

$ H _2 C _2 O _4+2 NaOH \longrightarrow Na _2 C _2 O _4+2 H _2 O$
$ m _{ eq } \text { of } H _2 C _2 O _4= m _{ eq } NaOH $
$50 \times 0.5 \times 2=25 \times M_{ NaOH } \times 1$
$\therefore M _{ NaOH }=2 M$
Now $1000 ml$ solution $=2 \times 40$ gram $NaOH$
$\therefore 50 ml$ solution $=4$ gram $NaOH$