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Q. $ 200\text{ }c{{m}^{3}} $ of an aqueous solution of a protein contains 1.26 g. of protein. The O.P. of such a solution at 300 K is found to be $ 2.57\times {{10}^{-3}} $ atm. Molar mass of protein is

AMUAMU 1999

Solution:

: Osmotic pressure $ =\frac{n}{V}RT $ $ 2.57\times {{10}^{-3}}=\frac{1.26}{M\times 200}\times 1000\times 0.0821\times 300 $ $ M=60377.0\text{ }gmo{{l}^{-1}} $ .