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Q. $10^{-6}\, M\, NaOH$ is diluted $100$ times. The $pH$ of the diluted base is

KCETKCET 2009Equilibrium

Solution:

$\left[ OH ^{-}\right]$ in the diluted base $=\frac{10^{-6}}{10^{2}}=10^{-8}$

Total $\left[ OH ^{-}\right]=10^{-8}+\left[ OH ^{-}\right]$ of water

$=\left(10^{-8}+10^{-7}\right)\,M$

$=10^{-8}[1+10]\, M$

$=11 \times 10^{-8} M $

$pOH =-\log 11 \times 10^{-8} $

$=-\log 11+8 \log 10 $

$=6.9586 $

$pH =14-6.9586$

$=7.0414 $