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Q. 1 mole of an ideal gas at STP is subjected to a reversible adiabatic expansion to double its volume. The change in internal energy (γ=1.4)

Thermodynamics

Solution:

For adiabatic expansion
T1Vγ11=T2Vγ12
T2=T1(V1V2)γ1=273(12)1.41
206K
dU=dW=Rγ1(T1T2)
=1×8.31(1.41)(273206.89)
1373J