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Q. $1 \,mL$ of $0.01 \,N \,HCl$ is added to $999\, mL$ solution of $0.1 \,N \,Na_2SO_4$. The $pH$ of the resulting solution will

UPSEEUPSEE 2013Equilibrium

Solution:

$As Na _{2} SO _{4}$ solution is neutral, it simply dilutes the $HCl$ solution from $1 \,mL$ to $1000\, mL$.

Now $\left[ H ^{+}\right] =\frac{0.01}{1000}=10^{-5}\, M $

$ \therefore \, pH =-\log \left[ H ^{+}\right] $

$=-\log\, 10^{-5} $

$=[-5 \,\log \,10]$

$pH =5 $