$\because$ 1 L of a gas at STP weighs = 1.97 g
$\therefore $ 22.4 L of the gas at STP will weigh = 1.97 $\times$ 22.4
= 44.1 g
$\therefore $ Molecular weight = 44.1 g
Molecular weight = 2 $\therefore $ vapour density
Vapour density = $\frac{44.1}{2} = 22.05$