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Tardigrade
Question
Chemistry
Which reaction is useful in exchange of halogen in alkyl chloride by iodide?
Q. Which reaction is useful in exchange of halogen in alkyl chloride by iodide?
1690
193
MHT CET
MHT CET 2019
Haloalkanes and Haloarenes
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A
Wurtz reaction
12%
B
Finkelstein reaction
75%
C
Reimer-Tiemann reaction
7%
D
Williamson synthesis
7%
Solution:
The reaction is useful in exchange of halogen in alkyl chloride by iodide is Finkelstein reaction. This reaction is used in preparation of alkyl iodide by the reaction of alkyl chloride, bromide with
N
a
I
in dry acetone
e.g.
C
H
3
C
H
2
B
r
+
N
a
I
Acetone
Δ
C
H
3
C
H
2
I
+
N
a
B
r