Raoult’s law states that the vapour pressure of a component over a solution is proportional to its mole fraction in solution.
The osmotic pressure ( π ) of a solution is given by the equation π = iCRT where M is the molarity of the solution.
The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl2 > KCl >CH3COOH > sucrose.