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Question
Chemistry
Which one of the following is not correct order of boiling points of the alkyl/aryl halides?
Q. Which one of the following is not correct order of boiling points of the alkyl/aryl halides?
2838
183
Haloalkanes and Haloarenes
Report Error
A
C
H
C
l
3
>
C
H
2
C
l
2
9%
B
C
H
3
(
C
H
2
)
3
Cl
>
C
H
3
(
C
H
3
)
2
Cl
13%
C
(
C
H
3
)
3
CCl
>
(
C
H
3
)
2
C
H
C
H
2
Cl
61%
D
C
H
3
(
C
H
2
)
3
Cl
>
C
H
3
C
H
2
C
H
ClC
H
3
17%
Solution:
(
C
H
3
)
3
CCl
>
(
C
H
3
)
2
C
H
C
H
2
Cl
is not correct as boiling point of
(
C
H
3
)
3
CCl
is smaller than
(
C
H
3
)
2
C
H
C
H
2
Cl
. It is due to large surface area and shorter alkyl chain.