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Question
Chemistry
Which of the following solutions is an example of negative deviation from Raoult’s law?
Q. Which of the following solutions is an example of negative deviation from Raoult’s law?
3148
179
WBJEE
WBJEE 2012
Solutions
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A
Acetone + Ethanol
8%
B
Carbon tetrachloride + Chloroform
10%
C
Acetone + Chloroform
77%
D
Water + Ethanol
5%
Solution:
C
H
3
COC
H
3
+
C
H
C
l
3
is an example of solution showing negative deviation from Raoult’s law since
A
−
B
attractions (acetone + chloroform) are more than
A
−
A
(acetone - acetone) and
B
−
B
(chloroform - chloroform) attractions.