Which of the following pairs represents linkage isomers ?

Question

Which of the following pairs represents linkage isomers ? (A) [Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4] (B) [Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2] (C) [CO(NH3)5 (NO3)]SO4 and [CO(NH3)5 (SO4)]NO3 (D) [PtCl2(NH3)4]Br2 and [PtBr2(NH3)4]Cl2

Tardigrade Admin · Accepted Answer

NCS- is ambidentate ligand and it can be linked through N (or) S

Q. Which of the following pairs represents linkage isomers ?

$[C u (N H_{3})_{4}] [PtC l_{4}]$ and $[Pt (N H_{3})_{4}] [C u C l_{4}]$

$[P d (PP h_{3})_{2} (NCS)_{2}]$ and $[P d (PP h_{3})_{2} (SCN)_{2}]$

$[CO (N H_{3})_{5} (N O_{3})] S O_{4}$ and $[CO (N H_{3})_{5} (S O_{4})] N O_{3}$

$[PtC l_{2} (N H_{3})_{4}] B r_{2} an d [PtB r_{2} (N H_{3})_{4}] C l_{2}$

$NC S^{-}$ is ambidentate ligand and it can be linked through N (or) S

Q. Which of the following pairs represents linkage isomers ?

[Cu(NH3​)4​][PtCl4​] and [Pt(NH3​)4​][CuCl4​]

[Pd(PPh3​)2​(NCS)2​] and [Pd(PPh3​)2​(SCN)2​]

[CO(NH3​)5​(NO3​)]SO4​ and [CO(NH3​)5​(SO4​)]NO3​

[PtCl2​(NH3​)4​]Br2​and[PtBr2​(NH3​)4​]Cl2​

NCS− is ambidentate ligand and it can be linked through N (or) S

$[C u (N H_{3})_{4}] [PtC l_{4}]$ and $[Pt (N H_{3})_{4}] [C u C l_{4}]$

$[P d (PP h_{3})_{2} (NCS)_{2}]$ and $[P d (PP h_{3})_{2} (SCN)_{2}]$

$[CO (N H_{3})_{5} (N O_{3})] S O_{4}$ and $[CO (N H_{3})_{5} (S O_{4})] N O_{3}$

$[PtC l_{2} (N H_{3})_{4}] B r_{2} an d [PtB r_{2} (N H_{3})_{4}] C l_{2}$

$NC S^{-}$ is ambidentate ligand and it can be linked through N (or) S