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Question
Chemistry
Which of the following are Lewis acids ?
Q. Which of the following are Lewis acids ?
3163
191
JEE Main
JEE Main 2018
Equilibrium
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A
P
H
3
and
BC
l
3
21%
B
A
lC
l
3
and
S
i
C
l
4
20%
C
P
H
3
and
S
i
C
l
4
10%
D
BC
l
3
and
A
lC
l
3
66%
Solution:
BC
l
3
−
electron deficient, incomplete octet
A
lC
l
3
−
electron deficient, incomplete octet
Ans-(4)
BC
l
3
and
A
lC
l
3
S
i
C
l
4
can accept lone pair of electron in
d
-orbital of silicon hence it can act as Lewis acid.
Although the most suitable answer is
(
4
)
.
However, both option
(
4
)
&
(
2
)
can be considered as correct answers.
e.g. hydrolysis of
S
i
C
l
4