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Question
Chemistry
The values of heat of formation of SO2 and SO3 are - 298.2 kJ and - 98.2 kJ. The heat of formation of the reaction, SO2 +(1/2)O2 arrow SO3 will be
Q. The values of heat of formation of
S
O
2
and
S
O
3
are
−
298.2
k
J
and
−
98.2
k
J
. The heat of formation of the reaction,
S
O
2
+
2
1
O
2
→
S
O
3
will be
6257
185
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JIPMER 2014
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A
+ 200 kJ
41%
B
- 356.2 kJ
17%
C
- 200 kJ
29%
D
- 396.2 kJ
13%
Solution:
Given,
(i)
S
+
O
2
⟶
S
O
2
;
Δ
H
=
−
298
⋅
2
k
J
(ii)
S
+
2
3
O
2
⟶
S
O
3
;
Δ
H
=
−
98
⋅
2
k
J
S
O
2
+
2
1
O
2
⟶
S
O
3
;
Δ
H
=
?
Subtracting eqn. (i) from eqn. (ii), we get,
⇒
S
O
2
+
2
1
O
2
⟶
S
O
3
Δ
H
=
−
98
⋅
2
+
298
⋅
2
=
+
200
k
J