Q.
The standard potentials, at 25oC, for the half- reactions are given against them below : Zn2++2e−ZnEo=−0.762VMg2++2e−MgEo=−2.37V When Zn dust is added to a solution of MgCl2,
Since, the standard reduction potential of Zn is higher than that of Mg. So, it is placed after Mg in the electrochemical series. Therefore, it cannot replace Mg from MgCl2.