Q.
The solution of Na in dry ether not only contains Nasolv. +and esolv. −but also contains Nasolv. −formed by the following disproportionation reaction. 2Na(s)Nasolv. ++Nasolv. −
The large sodide ion can be stabilized by making its
With cryptand-222, Na forms an unusual compound of the formula, [Na (cryptand-222)]Na− . The large cryp ligand completely shields the Na+ . ion and prevents it combining with Na− .