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Question
Chemistry
The rate constant for a first order reaction becomes six times when the temperature is raised from 350 K to 400 K. Calculate the activation energy for the reaction ( R = 8.314 JK - 1 mol - 1 )
Q. The rate constant for a first order reaction becomes six times when the temperature is raised from 350 K to 400 K. Calculate the activation energy for the reaction
(
R
=
8.314
J
K
−
1
m
o
l
−
1
)
3895
229
KEAM
KEAM 2006
Chemical Kinetics
Report Error
A
41.7
K
J
m
o
l
−
1
57%
B
4.17
k
J
m
o
l
−
1
11%
C
417
k
J
m
o
l
−
1
11%
D
0.417
k
J
m
o
l
−
1
7%
E
41760
k
J
m
o
l
−
1
7%
Solution:
log
k
1
k
2
=
2.303
R
E
−
a
[
T
1
−
T
2
T
2
−
T
1
]
k
1
k
2
=
6
,
T
1
=
350
K
,
T
2
=
400
K
log 6
=
2.303
×
8.314
E
a
[
400
×
350
400
−
350
]
0.7782 =
2.303
×
8.314
E
a
×
400
×
350
50
E
a
=
41.721
J
m
o
l
−
1
= 41.721 kJ
m
o
l
−
1