Q.
The plots of XA1 (on y-axis) vsYA1 (on x-axis) (where XA and YA are the mole fractions of liquid A in liquid and vapour phase respectively) is linear with slope and y-intercept respectively.
P=PA∘XA+PB∘(1−XΛ) and PA′XA=YAP=YA[PA∘XA+PB∘(1−XA)]
so, YA1=1+PA∘PB∘(XA1−1)
so, x=1+PA∘PB∘(y−1)
Hence ⇒(x−1)PA∘PB∘+1=y
so, y=mx+C gives the result