Q.
The maximum velocities of the photoelectrons ejected are v and 2v for the incident light of wavelength 400nm and 250nm on a metal surface respectively. The work function of the metal in terms of Planck’s constant h and velocity of light c is
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KEAMKEAM 2015Dual Nature of Radiation and Matter
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Solution:
According to Einstein's photoelectric equation, i.e. E=W0+Kmax
where, Kmax=21mvmax2= maximum kinetic energy of emitted electrons.
Given, λ1=400nm=400×10−9m λ2=250nm=250×10−9m
In the first condition, 400×10−9hc=21mv2+ϕ ...(i)
In the second condition, 250×10−19hc=21m(2v)2+ϕ 250×10−19hc=21m4v2+ϕ ...(ii)
From the Eq. (i), we get 21mv2=400×10−9hc−ϕ ...(iii)
Putting the value of Eq. (iii) in Eq. (ii), we get 250×10−19hc=4(400×10−19hc−ϕ)+ϕ 250×10−9hc=400×10−94hc−4ϕ+ϕ ⇒3ϕ=400×10−94hc−250×10−9hc ⇒3ϕ=100×10−9hc−250×10−9hc ⇒3ϕ=hc×109(1001−2501) ⇒3ϕ=hc×109(0.01−0.004) ∴3ϕ=6hc×106
Work function of the metal, ϕ=2hc×106J