Q.
The largest wavelength in the ultraviolet region of the hydrogen spectrum is 122nm . The smallest wavelength in the infrared region of the hydrogen spectrum (to the nearest integer) is
The series in UV region is Lyman series. Longest wavelength corresponds to minimum energy which occurs in the transition from n = 2 to n = 1.
Therefore 122=(121−221)R1 ... (i).
The smallest wavelength in the infrared region corresponds to a maximum energy of the Paschen series. λ=(321−∞1)R1 .... (ii)
Solving Eqs. (i) and (ii), we get λ=823.5nm