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Question
Chemistry
The increasing order of the boiling points for the following compounds is: (I) C 2 H 5 OH (II) C 2 H 5 Cl (III) C 2 H 5 CH 3 (IV) C 2 H 5 OCH 3
Q. The increasing order of the boiling points for the following compounds is :
(I)
C
2
H
5
O
H
(II)
C
2
H
5
Cl
(III)
C
2
H
5
C
H
3
(IV)
C
2
H
5
OC
H
3
3548
232
JEE Main
JEE Main 2017
Organic Chemistry – Some Basic Principles and Techniques
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A
(III) < (IV) < (II) < (I)
31%
B
(IV) < (III) < (I) < (II)
23%
C
(II) < (III) < (IV) < (I)
29%
D
(III) < (II) < (I) < (IV)
18%
Solution:
B.P.
∝
dipole moment
∝
H
-bonding
C
2
H
5
C
H
3
<
C
2
H
5
OC
H
3
<
C
2
H
5
Cl
<
C
2
H
5
O
H