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Question
Chemistry
The enthalpy of combustion at 25° C of H 2, cyclohexane ( C 6 H 12) and cyclohexene ( C 6 H 10) are -241,-3920 and -3800 kJ / mol respectively. The heat of hydrogenation of cyclohexene is :
Q. The enthalpy of combustion at
2
5
∘
C
of
H
2
, cyclohexane
(
C
6
H
12
)
and cyclohexene
(
C
6
H
10
)
are
−
241
,
−
3920
and
−
3800
k
J
/
m
o
l
respectively. The heat of hydrogenation of cyclohexene is :
3077
232
JIPMER
JIPMER 2006
Thermodynamics
Report Error
A
- 121 kJ/mol
B
+ 121 kJ/mol
C
- 242 kJ/mol
D
+ 242 kJ/mol
Solution:
H
2
+
2
1
O
2
⟶
H
2
O
Δ
H
=
−
241
k
J
... (i)
C
6
H
10
+
2
17
O
2
⟶
6
C
O
2
+
5
H
2
O
Δ
H
=
−
3800
k
J
...(ii)
C
6
H
12
+
9
O
2
⟶
6
C
O
2
+
6
H
2
O
Δ
H
=
−
3920
k
J
...(iii)
hydrogenation of cyclohexene-
C
6
H
10
+
H
2
⟶
C
6
H
12
Eq (i) }+ Eq (ii) - Eq (iii)
Δ
H
=
−
241
−
3800
−
(
−
3920
)
=
−
4041
+
3920
=
−
121
k
J