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Question
Chemistry
The enthalpy change when 2.63 g of phosphorus reacts with an excess of bromine according to the equation: 2 P (s)+3 Br 2(l) arrow 2 PBr 3(g) ; Δr H°=-243 kJ mol -1 will be
Q. The enthalpy change when
2.63
g
of phosphorus reacts with an excess of bromine according to the equation :
2
P
(
s
)
+
3
B
r
2
(
l
)
→
2
PB
r
3
(
g
)
;
Δ
r
H
∘
=
−
243
k
J
m
o
l
−
1
will be
1947
182
Thermodynamics
Report Error
A
103
k
J
B
10.3
k
J
C
20.6
k
J
D
24.3
k
J
[Given: Molar mass of phosphorus
=
30.97
g
m
o
l
−
1
]
Solution:
Molar mass of phosphorus
=
30.97
m
o
l
−
1
2
P
(
s
)
+
3
B
r
2
(
l
)
→
2
PB
r
3
(
g
)
,
Δ
H
∘
=
−
243
k
J
m
o
l
−
1
We know,
30.97
g
(
1
mole
)
of
P
when reacted liberates
243
k
J
of energy
1
g
of
P
when reacted will liberate
=
30.97
243
k
J
and
2.63
g
of
P
when reacted liberates
=
30.97
243
×
2.63
=
20.64
k
J
Hence, the enthalpy change will be
=
20.64
k
J