Q.
The empirical formula of a non-electrolyte is CH2O. A solution containing 6g of the compound exerts the same osmotic pressure as that of 0.05M glucose solution at the same temperature. The molecular formula of the compound is
Solutions having same osmotic pressure, at a given temperature, have same concentration.
Concentration of compound = concentration of glucose <br/><br/>M×16=0.05<br/>M=0.056=120<br/>(CH2O)=12+2+16=30<br/>n= empirical formula mass molecular mass =30120=4<br/><br/>
Hence, Molecular formula (CH2O)4=C4H8O4