Q.
The correct order of increasing bond angles in the following triatomic species is
3553
230
AIPMTAIPMT 2008Chemical Bonding and Molecular Structure
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Solution:
According to VSEPR theory,
The order of repulsion of electrons is lp-lp repulsion > lp-bp repulsion > bp-bp repulsion
Higher the number of lone pair of electrons (greater is repulsion) lower is the bond angle and vice-versa.
In NO2− one lone pair of electron is present while in NO2+ no lone xav of electron Is present. Hence, the correct order of bend angles is NO2−<NO2<NO2+