The order of bond dissociation energy of hydrogen halide (or halogen acid) is as HydrogenhalideBonddissociationHF>HCl>HBr>HI energyKJmol−1566431366299
Bond dissociation energy ∝ heat of formation
As bond dissociation energy decreases the heat of formation of halogen acids is also decreases. Hence, the order of heat of formation of halogen acids is HF>HCl>HBr>HI