Tollen's reagent is ammoniacal silver nitrate solution. It is prepared as follows AgNO3+ (excess) NH4OH⟶ Tollen’s reagent [Ag(NH3)2]OH+H2O
Tollen's reagent is a mild oxidising agent and oxidise only aldehydes to form silver mirror. It is used to differentiate between aldehydes and ketones RCHO+2[Ag(NH3)2]OH⟶ RCOONH4+Silver mirror2Ag↓+3NH3+H2O