Photochemical smog is initiated by the photochemical dissociation of NO2 and the resulting secondary reactions involving unsaturated hydrocarbons, other organic compounds and free radicals, leading to the formation of organic peroxides and ozone, NO2(g)UV lightNO(g)+[O]] O2(g)+[O]→O3(g)
Hydrocarbons +O3,O2,O,NO2, NO :
Peroxides, peroxyacetyl nitrate, formaldehyde, ozone aldehyde, acrolein etc. (oxidized hydrocarbons)
These oxidized hydrocarbons and ozone in the presence of humidity cause photochemical smog, which dissipates at night.