Q.
The bond length of HCl molecule is 1.275A˚ and its dipole moment is 1.03 D. The ionic character of the molecule (in percent) (charge of electron 4.8×10−10 esu) is
2392
203
Chemical Bonding and Molecular Structure
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Solution:
% of ionic character =μtheoreticalμexperimental×100 μtheoretical=e×d=4.8×10−10esu×1.275×10−8cm =6.12×10−18esucm=6.12D μexperimental=1.03D ∴% of ionic character =6.121.03×100=16.83