pCO2=0.30−0.31mmHg in air.
Air contains 0.04% of carbon dioxide.
This means that in every 100 molecules of air, 0.04 will be CO2 molecules.
The number of moles of carbon dioxide in 100 molecules of air will be nCO2=0.04 molecules ×NA=0.04×NA
The total number of moles in the sample of air will be ntotal=100 molecules ×NA=100NA
This means that mole fraction of carbon dioxide in the mixture will be XCO2=100NA0.04NA=0.0004
Carbon dioxide’s partial pressure in air will thus be pCO2=0.0004×760mmHg =0.304mmHg∴ We can say it ranges between 0.30−0.31mmHg