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Chemistry
Sulphuryl chloride (SO2Cl2) reacts with white phosphorus (P4) to give
Q. Sulphuryl chloride
(
S
O
2
C
l
2
)
reacts with white phosphorus
(
P
4
)
to give
4284
178
WBJEE
WBJEE 2015
The p-Block Elements - Part2
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A
PC
l
5
,
S
O
2
68%
B
OPC
l
3
,
SOC
l
2
11%
C
PC
l
5
,
S
O
2
,
S
2
C
l
2
16%
D
OPC
l
3
,
S
O
2
,
S
2
C
l
2
6%
Solution:
When sulphuryl chloride
(
S
O
2
C
l
2
)
reacts with white phosphorus
(
P
4
)
, it give phosphorus pentachloride
(
PC
l
5
)
and' sulphur dioxide
(
S
O
2
)
. The reaction is as follows:
P
4
+
10
S
O
2
C
l
2
⟶
4
PC
l
5
+
10
S
O
2