Q.
Separation energy of a hydrogen like ion from its third excited state is 2.25 times the separation energy of hydrogen atom from its first excited state. Find out the atomic number of this hydrogen like ion.
Let the separation energy of the ion in third excited state (n=4) be E . Then E=13.6×Z2×161eV
and in the first excited state (n=2) , EH=13.6×41eV ⇒EHE=Z2×164 ⇒EH2.25EH=4Z2 ⇒Z2=9⇒Z=3