Q.
Pure sodium (Na) is a good conductor of electricity because the 3s and 3p atomic bands overlap to form a partially filled conduction band. By contrast the ionic sodium chloride (NaCl) crystal is
In sodium chloride the Na+ and Cl− ions both have noble gas electron configuration corresponding to completely filled bands. Since the bands do not overlap, there must be a gap between the filled bands and the empty bands above them, so NaCl is an insulator.