Silver metal is obtained by Mac-Arthur forest process which is called cyanide process.
The concentrated ore of argentite is treated with dilute NaCN solution and a current of O2 is continuously passed.
Silver sulphide goes into solution in the form of soluble complex sodium argentocyanide. 2Ag2S+8NaCN+O2+2H2O→4Na[Ag(CN)2]+4NaOH+2S
The soluble complex is treated with zinc dust, when silver gets precipitated. 2Na[Ag(CN)2]+Zn→Na2[Zn(CN)4]+2Ag↓