Q.
Monochromatic radiation of wavelength λ is incident on a hydrogen sample in ground state. Hydrogen atoms absorb a fraction of light and subsequently emit radiation of six different wavelengths. Find the value of λ .
As the hydrogen atoms emit radiation of six different wavelengths, some of them must have been excited to n=4 , The energy in n=4 state is E4=42E1=−1613⋅6eV=−0⋅85eV.
The energy needed to take a hydrogen atom from its ground state to n=4 is 13.6 eV - 0.85 eV = 12.75 eV .
The photons of the incident radiation should have 12.75eV of energy. So λhc=12⋅75eV
or , λ=12⋅75eVhc =12⋅75eV1242eVnm = 97.5 nm .