Q.
Knowing that radius of Na+>Mg2+ and radius of S2−>Cl−, predict which compound will be least soluble in polar solvent?
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Chemical Bonding and Molecular Structure
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Solution:
Smaller size of cation, larger size of anion and high charge favours polarisation thus more covalenf character. As covalent character increases, solubility in polar solvent decreases because covalent compounds are non-polar.