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Question
Chemistry
In which of the following reactions H2O2 acts as a reducing agent? (a) H2O2 + 2H+ + 2e- arrow 2H2O (d) H2O2 - 2e- arrow O2 + 2H+ (c) H2O2 + 2e- arrow 2OH- (d) H2O2 + 2OH- - 2e- arrow O2 + 2H2O
Q. In which of the following reactions
H
2
O
2
acts as a reducing agent?
(a)
H
2
O
2
+
2
H
+
+
2
e
−
→
2
H
2
O
(d)
H
2
O
2
−
2
e
−
→
O
2
+
2
H
+
(c)
H
2
O
2
+
2
e
−
→
2
O
H
−
(d)
H
2
O
2
+
2
O
H
−
−
2
e
−
→
O
2
+
2
H
2
O
3249
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JEE Main 2014
Redox Reactions
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A
(a) and (b)
11%
B
(c) and (d)
14%
C
(a) and (c)
23%
D
(b) and (d)
53%
Solution:
The reducing agent oxidises itself.
(a)
H
2
O
2
−
1
+
2
H
+
+
2
e
−
⟶
2
H
2
O
−
2
(b)
H
2
O
2
−
1
−
2
e
⟶
O
2
+
2
H
+
(c)
H
2
O
2
−
1
+
2
e
⟶
2
O
H
−
2
(d)
H
2
O
2
−
1
+
2
O
H
−
−
2
e
⟶
O
2
+
H
2
O
Note: Powers of 'O' are oxidation number of 'O' in the compound.