The oxidation number of elements have been mentioned in brackets as shown below:
a. NO2(x=4) and N2O4(x=4)
Difference in oxidation state of N=0.
b. P2O5(x=+5) and P4O10(x=+5)
Difference in oxidation state of P is zero.
c. N2O(x=1) and NO(x=2)
Difference in oxidation state of N=1.
d. SO2(x=4) and SO3(x=6)
Difference in oxidation state of S=2.
Hence, the difference in oxidation states of underlined elements is greatest in SO2.