Q. In which book, "Binomial nomenclature" has been used for the first time?

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Solution:

Binomial Nomenclature is the method of scientific naming given by C Linnaeus (1735) in his book Systema Naturae and later in Species Plantarum (1753). He used two latin words for any organism, the first being generic name and the second is specific name.
In Historia Plantarum, plants were described by Theophrastus (Father of Botany).
Historia Naturalis was published by Pliny.