Q.
In the following species, the one which is likely to be the intermediate during benzoin condensation of benzaldehyde, is
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WBJEEWBJEE 2013Aldehydes Ketones and Carboxylic Acids
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Solution:
When benzaldehyde is heated with aqueous ethanolic NaCN or KCN, it dimerises to form an α-hydroxy ketone called benzoin, and this reaction is formed as benzoin condensation. It involves self condensation of an aromatic aldehyde in the presence of CN−as catalyst.