Q.
In a single isolated atom of He+ion an electron makes transition from third excited state to ground state by emitting only two photons. The higher energy (in eV ) will be:
Since electron is coming from 3rd excited state to ground state by emitting only two photrons, it can be 4→3 and 3→1
Hence, higher energy value will be ΔE3→1=(13.6−1.5)×22=48.4eV