Q.
If K1 and K2 are the respective equilibrium constants for the two reactions, XeF6(g)+H2O(g)⇌XeOF4(g)+2HF(g) XeO4(g)+XeF6(g)⇌XeOF4(g)+XeO3F2(g)
The equilibrium constant of the reaction, XeO4(g)+2HF(g)⇌XeO3F2(g)+H2O(g)
XeF6(g)+H2O(g)⇌XeOF4(g)+2HF(g) K1=[XeF6][H2O][XeOF4][HF]2 ...(i) XeO4(g)+XeF6(g)⇌XeOF4(g)+XeO3F2(g) K2=[XeO4][XeF6][XeOF4][XeO3F2] ...(ii)
For the reaction, XeO4(g)+2HF(g)⇌XeO3F2(g)+H2O(g)K=[XeO4][HF]2[XeO3F2][H2O] ...(iii) ∴ From Eqs. (i), (ii) and (iii) K=K1K2