The balanced chemical reaction is 3BaCl2+2Na3PO4→Ba3(PO4)2+6NaCl
In this reaction, 3 moles ofBaCl2 combines with 2 moles of Na3PO4
Hence, 0.5 mole of of BaCl2 require =32×0.5=0.33 mole of Na3PO4
Since, available Na3PO4(0.2 mole) is less than required mole (0.33),
it is the limiting reactant and would determine the amount of product Ba3(PO4)2 ∵2 moles of Na3PO4 gives 1 mole Ba3(PO4)2 ∴0.2 mole of Na3PO4 would give 21×0.2 =0.1 mole Ba3(PO4)2