Q.
Hydrogen is at temperature T and helium is at temperature 2T. The internal energy of both gases is the same. The ratio of number of moles of hydrogen and helium gases is
2601
191
UP CPMTUP CPMT 2011Kinetic Theory
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Solution:
Internal energy of a gas, U=nCVT
where n is the number of the moles of a gas and Cv is the molar specific heat at constant volume and T is the temperature of the gas.
As hydrogen is a diatomic gas, ∴(CV)H2=25R
As helium is a monatomic gas, ∴(CV)He=23R
According to the question UH2=UHe ⇒nH2×(CV)H2×TH2 =nHe×(CV)He×THe ∴nH2×25R×T =nHe×23R×2T nHenH2=56