Alcohols and phenols can be distinguished by the following tests,
I. Reaction with ferric chloride: Phenols react with neutral ferric chloride solution to give blue, violet or green colouration whereas alcohols do not react.
II. Bromine water test: Phenols react with bromine water to give a white precipitate of 2,4,6-tribromophenol while alcohols do not.
III. Coupling reaction: Phenols react with diazonium salts in basic solution to form yellow or orange coloured dyes but alcohols do not react.