For a monoatomic gas like argon, Cv = 3 cal mol−1, Cp = 5 cal mol−1.
Molar heat capacity is the heat required to raise the temperature of 1 mole of the gas by 1∘ 40 g of argon = 1 mole.
Hence, heat required to raise the temperature from 40∘ to 100∘C at constant volume = 3 × (100 - 40) = 180 cal