Halogen acids react with alcohols to form alkyl halides. The reaction follows a nucleophilic substitution mechanism. What will be the major product of the following reaction?

Question

Halogen acids react with alcohols to form alkyl halides. The reaction follows a nucleophilic substitution mechanism. What will be the major product of the following reaction? (A)  (B)  (C)  (D) CH3CH2CH2CH2CH2Cl

Tardigrade Admin · Accepted Answer

<img class="img-fluid question-image" alt="image" src="https://cdn.tardigrade.in/img/question/chemistry/0e28d0a7aea97dc032265b739caf095b-.png" /> The intermediate in the reaction is secondary carbocation that can change to more stable teritary carbocation by 1,2 -hydride shift. So, the major product is CH 3- C ( CH 3)( Cl )- CH 2- CH 3

Q. Halogen acids react with alcohols to form alkyl halides. The reaction follows a nucleophilic substitution mechanism. What will be the major product of the following reaction?

$C H_{3} C H_{2} C H_{2} C H_{2} C H_{2} Cl$

The intermediate in the reaction is secondary carbocation that can change to more stable teritary carbocation by 1,2 -hydride shift. So, the major product is $C H_{3} -$ $C (C H_{3}) (Cl) - C H_{2} - C H_{3}$

Q. Halogen acids react with alcohols to form alkyl halides. The reaction follows a nucleophilic substitution mechanism. What will be the major product of the following reaction?

CH3​CH2​CH2​CH2​CH2​Cl

The intermediate in the reaction is secondary carbocation that can change to more stable teritary carbocation by 1,2 -hydride shift. So, the major product is CH3​− C(CH3​)(Cl)−CH2​−CH3​

$C H_{3} C H_{2} C H_{2} C H_{2} C H_{2} Cl$

The intermediate in the reaction is secondary carbocation that can change to more stable teritary carbocation by 1,2 -hydride shift. So, the major product is $C H_{3} -$ $C (C H_{3}) (Cl) - C H_{2} - C H_{3}$