Given that the half-life of a radioactive substance is 20min. So, t1/2=20min.
For 20% decay, we have 80% of the substance left, hence 10080N0=N0e−λt20...(i)
where N0= initial undecayed substance and t20 is the time taken for 20% decay.
For 80% decay, we have 20% of the substance left, hence 10020N0=N0e−λt80...(ii)
Dividing Eq. (i) and Eq. (ii), we get 4=eλ(t80−t20) ⇒ln4=λ(t80−t20)
(taking log on both sides) ⇒2ln2=t1/20.693(t80−t20) ⇒t80−t20=2×t1/2=40min