Q.
Given that, the solubility product Ksp of AgCl is 1.8×10−10, the concentration of Cl− ions that must be exceeded before AgCl will precipitate from a solution containing 4×10−3MAg+ ions is
Ksp=[Ag+][Cl−] [Cl−]=4×10−31.8×10−10 =4.5×10−8M
If concentration of Cl− exceeds 4.5×10−8M then ionic product becomes greater than Ksp and precipitation takes place.